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MAE115 Applied Engineering Thermodynamics
创建日期：2024-08-27 18:13:55
所属分类：化学chemistry
标签： MAE115
Applied Engineering Thermodynamics

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MAE115  Applied Engineering Thermodynamics


Examination 

Conceptual Short Answer (25 points):

1.   Answer the following questions with a single short sentence, expression, or word.

a.   For a given molecule, what type of energy does hf(o) represent?

b.   State the direction of energy flow in a system to produce the following molecules:

a.   Acetylene (C2H2  , hf(o) = +226,730 KJ/Kmol)

b.   Propane (C3H6, hf(o) = 103,850 KJ/Kmol)

c.   Hydrogen (H2, hf(o) = 0 KJ/Kmol)

c.   Will a mixture of gases always reach chemical equilibrium quickly?

d.   You have Kp  data for the following reaction: H2  + ? O2 ? H2O. If the stoichiometric coefficients of this reaction are doubled, how can you use the original Kp data?

e.   Using the table to the right, at approximately what temperature will the forward reaction occur as frequently as the reverse reaction?

H2  2 H

Temperature (K)

ln(KP)

2200

-2.534

2400

-1.516

2600

-0.609

2800

0.202

3000

0.934

3500

2.486

4000

3.725

4500

4.743

5000

5.590

General Thermodynamic Properties (20 points):

2.   Prove that the enthalpy of an ideal gas is a function of temperature only.

Recall:

Combustion (40 points):

3.   A mixture of 1 kmol Methane (CH4) and 80% excess air, both originally at 350 K, are combusted at a constant pressure of 1 atm

Determine the following:

(a) The balanced chemical reaction if complete combustion occurs (b) The equivalence ratio φ

(c) Using the table below, calculate how much energy is present in the reactants only

(d) You need to calculate the adiabatic flame temperature for this mixture. You’re first

temperature guess produces a total combustion products enthalpy of -40,000 kJ/kmol. Based on the reactant enthalpy calculated in (c), should your next temperature guess be higher or lower?

(e) If combustion were incomplete, and CO existed in the products, what system of equations (neglecting the first law for a reacting system) would be used to solve for the concentration of products? Assume the only dissociation to create CO is the following the equilibrium reaction: CO2 ? CO + ? O2.

(f)  If the air and methane mixture were initially heated to 600 K before any chemical

reaction occurred, would the adiabatic flame temperature increase, decrease, or remain the same? Provide a one sentence explanation for your answer.

(g) Would the adiabatic flame temperature increase or decrease if the combustion occurred at constant volume? Provide a one sentence explanation for your answer.

Species

Enthalpy of formation, hfo (kJ/kmol)

Enthalpy at 298 K (kJ/kmol)

Enthalpy at 350 K (kJ/kmol)

CH4

-74,850

11,744

13,824

O2

0

8,682

10,213

N2

0

8,669

10,180

Mixtures (15 points):

4.   An insulated rigid tank contains a gas mixture. The gas mixture consists of 30 percent hydrogen, 40 percent nitrogen, and 30 percent Argon by volume. Determine the heat addition per kg required to raise the temperature of the mixture by 100 K. Assume constant specific heats.

Species

CP (kJ/kg*K)

CV (kJ/kg*K)

MW (kg/kmol)

N2

1.039

0.743

28

H2

14.307

10.183

2

Ar

0.5203

0.3122

40

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关键词一 关键词二 关键词三 关键词四 关键词五 和法规和的发更好的风格和 ECON 615 FINC 612 CSC148 COMP 639 ACCT 203 ACCT 211 PSYC 101 MTH2009 COMP52315 PSYCO 432 statistics MATH4063 11 xxx 1 MA1MSP MAST30028 MATH3888 CS341 EEE30002 ES2F5 MCD4160 CC0933 ECON 1101 MCHM3001 CHEM3118 COMMGMT 2511 COMP41280 STAT 631 24T1 IRE379 SENG365 ECON433 FIT3139 MATH4602 LING5621M FINS5516 ECON3208 MN2177 L2 SM EEET1415 Finance DS4023 COMP3004 7CCSMRTS K1S5B6 Stat230 CSCI4211 CSI2132 ECON30130 MAS6100 ENVS222 COM2107 INFO1112 STAT 4004 FIT2100 comp2022 COMP4691 Physics 307 Econ 659 probability CSCI316 fir29 CSCI203 COMP3160 COMP6714 INFO1113 Physics 7B Physics Photonics S203031 STAT2005 COMP90015 CSCI 2110 CSCC46 Information CSC477 COMP4650 Statistical COMP 346 COMP1017 ELEC340 MATH1007 Programming function STAT 244 CS 134 Java cse13s Math 108A FW20 ECON3389 CSE 130 Science 331 COMP9020 engineering COSC 445 CSE 5523 GAME2012 visualization MATH 235 Math 370 CSC343 COGS 108 EE524 COMP10200 STAT 416 3FK4 MSCI 311 ECON6113 ACC40700 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