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GEOL0017 Assessed Practical

创建日期：2024-06-13 15:49:44

所属分类：化学chemistry

标签： GEOL0017

Assessed Practical

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GEOL0017 Part 2 Assessed Practical

Please submit your answers to this exercise on Moodle by
1pm, Friday 5 April
This practical is designed to apply the principles of stable isotope geochemistry
introduced in Week 7 and studied for several different isotope systems in weeks 8–10.
It addresses the following learning outcomes:
 Understand and apply stable isotope notation.
 Use stable isotope ratios to constrain oceanic mass balance calculations.
The number of marks for each question is given in brackets, e.g., (2 marks). The total
available is 40 marks. This practical is worth 15% of your final mark for GEOL0017.
Part A: Stable Isotope Basics (16 marks)
Choose one stable isotope system. Complete the following exercise using your chosen
element as an example. Write down your chosen element below.
Chosen Element: ………………………
Grading Note: The mark for this part will be capped at 50% if you choose an element that we
study in class (any of: H, O, C, N, B, S, Mo, Cr)!
Complete the following tasks.
a) (2 marks) List the main isotopes of the element you have chosen, noting whether each
isotope is stable or radiogenic. Note: You may ignore short-lived radioisotopes.
b) (2 marks) Which stable isotope ratio is reported in published literature? If more than one
ratio is reported, write the ratio that you find reported most often.
c) (2 marks) Which isotopic reference standard is most commonly used?
d) (2 marks) Write down the definition of δ-notation for your element, using your answers to
part b) and c).
e) (8 marks) Find one recent paper (published since 2015) that reports data for your isotope
system. Briefly summarise the findings (Max. 200 words). Include the paper reference in
your answer.
Grading Note: You must not choose the same paper as another student. You should email
me ([email protected]) with your chosen paper by Thursday 4 April (or earlier). If another
student has already selected the paper you have chosen, I will tell you to choose again. If you
do not tell me the paper you have chosen, and you select the same paper as someone else,
you will receive zero marks for this part.
Dr Susan Little GEOL0017
Part B: Oceanic mass balance (24 marks)
Residence time is an important concept in many aspects of Earth Sciences. It refers to the
average lifetime of a substance (e.g., sulfate) in a reservoir (e.g., the ocean) of interest.
Residence time is calculated using this formula:
τ= A
F¿
(Equation 1)
Where τ is residence time, A is the total amount of substance in the reservoir (e.g., in moles),
and Fin is the flux into the reservoir per unit time (e.g., mol yr-1).
a) (1 mark) Sulfate concentrations in the modern ocean are 28 mmol kg-1. There are 1.37 ×
1021 kg of water in the ocean. Calculate many moles of sulfate there are in the ocean.
b) (3 marks) Rivers are the main input flux of sulfate to the modern ocean, with a flux of 3 ×
1012 mol yr-1. Calculate the residence time of sulfate in the ocean. Is the residence time of
sulfate longer or shorter than the ocean mixing time?
Figure 1 shows a simple one-box model of the oceanic mass balance of sulfate.
Figure 1. One-box model of the oceanic mass balance of sulfate.

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